{ "cells": [ { "cell_type": "markdown", "metadata": {}, "source": [ "# 2.5 – Fractional Conversion Yield Selectivity Excess\n", "\n", "---" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "## 2.5.0 – Learning Objectives\n", "\n", "By the end of this section you should be able to:\n", "\n", "1. Understand the concepts of fractional conversion, yield, selectivity, and percent excess.\n", "\n", "---" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "## 2.5.1 – Introduction\n", "\n", "Fractional conversion, yield, selectivity, and percent excess are all important methods of describing how a chemical reaction progresses. They are useful values to solve material balances.\n", "\n", "---" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "## 2.5.2 – Fractional Conversion\n", "\n", "Fractional conversion is defined as the number of moles of a compound that reacted divided by the amount of the moles\n", "that were fed. \n", "\n", "$$Fractional \\space conversion = \\frac{\\dot{n}_{consumed}}{\\dot{n}_{input}} $$ \n", "\n", "Another useful form of writing fractional conversion is \n", "\n", "$$Fractional \\space conversion = \\frac{\\dot{n}_{input}-\\dot{n}_{output}}{\\dot{n}_{input}}$$\n", "\n", "---" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "## 2.5.3 – Yield (Fractional Yield)\n", "\n", "Yield is defined as the moles of product formed divided by the ideal number of moles formed. \n", "\n", " $$ Yield = \\frac{\\dot{n}_{formed}}{\\dot{n}_{ideal}} $$\n", " \n", "The ideal number of moles formed is assuming that the limiting reactant reacts fully and that there are no side reactions. \n", "\n", "---" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "## 2.5.4 – Selectivity\n", "\n", "Selectivity is defined as the moles of desired __products__ formed divided by the moles of undesired __products__ formed.\n", "\n", " $$ Selectivity= \\frac{\\dot{n}_{product\\space desired}}{\\dot{n}_{product\\space undesired}} $$\n", "\n", "---" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "## 2.5.5 – Percent Excess\n", "\n", "Percent excess is defined as the number of moles that are unreacted divided by the moles fed.\n", "$$Percent \\space excess = \\frac{\\dot{n}_{input}-\\dot{n}_{consumed\\space theoretically}}{\\dot{n}_{consumed\\space theoretically}}$$\n", "\n", "__Note:__ any of these terms above can be expressed as a percent (by multiplying 100 to the values)" ] }, { "cell_type": "code", "execution_count": null, "metadata": { "collapsed": true }, "outputs": [], "source": [] } ], "metadata": { "kernelspec": { "display_name": "Python 3", "language": "python", "name": "python3" }, "language_info": { "codemirror_mode": { "name": "ipython", "version": 3 }, "file_extension": ".py", "mimetype": "text/x-python", "name": "python", "nbconvert_exporter": "python", "pygments_lexer": "ipython3", "version": "3.6.1" } }, "nbformat": 4, "nbformat_minor": 2 }